Chlorate ion in drinking water? New regulation, old challenges, and the solutions

Attention, water utilities! Since July 1, 2024, stricter limits apply to chlorate ion levels in drinking water. But what exactly is the chlorate ion? Why is it a problem? How can its concentration be reduced? And what can a utility or operator do to comply with the new rules?

What is chlorate ion and how does it enter drinking water?

The chlorate ion (ClO₃⁻) is a decomposition byproduct of sodium hypochlorite (NaOCl), commonly known as bleach. Sodium hypochlorite is widely used for disinfecting drinking water.

The issue begins when:

  • bleach is stored for long periods,
  • kept in warm environments, or
  • used in high concentrations.

These all accelerate decomposition – increasing chlorate levels in the solution, and ultimately in the water supply.

New limit: 0.25 mg/l

Az ivóvíz minőségi követelményeiről és az ellenőrzés rendjéről szóló 5/2023. According to Government Regulation 5/2023 (I.12.) on drinking water quality and monitoring requirements, the maximum permissible chlorate ion concentration is 0.25 mg/l, 2026. mandatory for all water suppliers starting January 12, 2026. This regulation aligns with the provisions of the (EU) 2020/2184 directive on the quality of water intended for human consumption.

This is especially critical in areas where:

  • breakpoint chlorination (high-dose bleach) is used,
  • ammonium or iron–manganese removal technologies are applied.

Why is chlorate ion a problem?

Accumulation of chlorate in drinking water may pose health risks, particularly for:

  • young children,
  • individuals with kidney disease,
  • and those with thyroid disorders.

In addition, exceeding the legal limit during regulatory inspections can lead to serious consequences – fines, reputational damage, or even water supply restrictions.

What can be done? – Step-by-step solutions

  1. Optimize storage conditions
  • Reduce the storage time of bleach – order smaller batches more frequently
  • Store in a cool, dark place in sealed containers
  • Use lower-concentration solutions (e.g. 45 g/l instead of 90 g/l)
  • Regularly monitor chlorate ion levels
  1. Technological modifications
  • Switch to chlorine gas disinfection (no chlorate, but high investment and complex permitting)
  • Use potassium permanganate or ozone as oxidizing agents (they don’t generate chlorate)
  1. Innovative solution: on-site chlorine generation

On-site systems like our ClearGenX generators produce active chlorine from ordinary salt tablets via electrolysis. These:

  • generate fresh chlorine with no chlorate accumulation
  • eliminate the need for transporting or storing hazardous chemicals
  • operate with cloud-based control and SCADA integration
  • are safer and more cost-effective in the long run

 

In summary: Proactive response is key

The chlorate ion issue is not an isolated case – it’s a growing technological and regulatory challenge for many water utilities. The good news? Forward-thinking, practical solutions already exist.

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